Showing posts with label manufacturer. Show all posts
Showing posts with label manufacturer. Show all posts

Saturday, February 21, 2015

CN - Major Speedy Prototyping China Manufacturer Provides Higher Precision Metal ...

Steven F. Udvar-Hazy Center: P-40 Warhawk with “sharktooth” nose


Image by Chris Devers
See a lot more photos of this, and the Wikipedia write-up.


Specifics, quoting from Smithsonian National Air and Space Museum | Curtiss P-40E Warhawk (Kittyhawk IA):


Whether known as the Warhawk, Tomahawk, or Kittyhawk, the Curtiss P-40 proved to be a productive, versatile fighter in the course of the very first half of Globe War II. The shark-mouthed Tomahawks that Gen. Claire Chennault’s &quotFlying Tigers&quot flew in China against the Japanese stay among the most common airplanes of the war. P-40E pilot Lt. Boyd D. Wagner became the very first American ace of Globe War II when he shot down six Japanese aircraft in the Philippines in mid-December 1941.


Curtiss-Wright built this airplane as Model 87-A3 and delivered it to Canada as a Kittyhawk I in 1941. It served until 1946 in No. 111 Squadron, Royal Canadian Air Force. U.S. Air Force personnel at Andrews Air Force Base restored it in 1975 to represent an aircraft of the 75th Fighter Squadron, 23rd Fighter Group, 14th Air Force.


Donated by the Exchange Club in Memory of Kellis Forbes.


Manufacturer:
Curtiss Aircraft Organization


Date:

1939


Nation of Origin:

United States of America


Dimensions:

Overall: 330 x 970cm, 2686kg, 1140cm (10ft 9 15/16in. x 31ft 9 7/8in., 5921.6lb., 37ft 4 13/16in.)


Materials:

All-metal, semi-monocoque


Physical Description:

Single engine, single seat, fighter aircraft.


Lengthy Description:

Whether or not it was the Tomahawk, Warhawk, or Kittyhawk, the Curtiss P-40 was a profitable and versatile fighter aircraft throughout the first half of World War II. The shark-mouthed Tomahawks that General Claire Chennault led against the Japanese stay amongst the most well-liked airplanes of the war. In the Phillipines, Lt. Boyd D. Wagner became the 1st American ace of Globe War II although flying a P-40E when he shot down six Japanese aircraft for the duration of mid-December 1941. P-40s had been 1st-line Army Air Corps fighters at the start of the war but they quickly gave way to more sophisticated styles such as the Republic P-47 Thunderbolt and the Lockheed P-38 Lightning (see NASM collection for each aircraft). The P-40 is not ranked amongst the best all round fighters of the war but it was a rugged, successful design and style obtainable in massive numbers early in the war when America and her allies urgently required them. The P-40 remained in production from 1939 to the finish of 1944 and a total of 13, 737 were built.


Design and style engineer Dr. Donovan R. Berlin layed the foundation for the P-40 in 1935 when he developed the agile, but lightly-armed, P-36 fighter equipped with a radial, air-cooled engine. The Curtiss-Wright Corporation won a production contract for 210 P-36 airplanes in 1937-the largest Army airplane contract awarded given that Planet War I. Worldwide, fighter aircraft designs matured swiftly during the late 1930s and it was quickly obvious that the P-36 was no match for newer European styles. High altitude efficiency in distinct became a priceless commodity. Berlin attempted to enhance the P-36 by redesigning it in to accommodate a turbo-supercharged Allison V-1710-11 inline, liquid-cooled engine. The new aircraft was designated the XP-37 but proved unpopular with pilots. The turbo-supercharger was not trustworthy and Berlin had placed the cockpit also far back on the fuselage, restricting the view to the front of the fighter. Nonetheless, when the engine was not providing trouble, the much more-streamlined XP-37 was much more quickly than the P-36.


Curtiss attempted once more in 1938. Berlin had modified one more P-36 with a new Allison V-1710-19 engine. It was designated the XP-40 and very first flew on October 14, 1938. The XP-40 looked promising and Curtiss presented it to Army Air Corps leaders who evaluated the airplane at Wright Field, Ohio, in 1939, along with several other fighter proposals. The P-40 won the competition, following some modifications, and Curtiss received an order for 540. At this time, the armament package consisted of two .50 caliber machine guns in the fuselage and four .30 caliber machine guns in the wings.


After production began in March 1940, France ordered 140 P-40s but the British took delivery of these airplanes when Paris surrendered. The British named the aircraft Tomahawks but found they performed poorly in high-altitude combat more than northern Europe and relegated them to low-altitude operations in North Africa. The Russians purchased much more than two,000 P-40s but details of their operational history stay obscure.


When the United States declared war, P-40s equipped several of the Army Air Corps’s front line fighter units. The plucky fighter at some point saw combat in nearly every theater of operations being the most successful in the China-Burma-India (CBI) Theater. Of all the CBI groups that gained the most notoriety of the complete war, and remains to this day synonymous with the P-40, is the American Volunteer Group (AVG) or the Flying Tigers. The unit was organized right after the Chinese gave former U. S. Army Air Corps Captain Claire Lee Chennault virtually 9 million dollars in 1940 to acquire aircraft and recruit pilots to fly against the Japanese. Chennault’s most critical assistance inside the Chinese government came from Madam Chiang Kai-shek, a Lt. Colonel in the Chinese Air Force and for a time, the service’s general commander.


The cash from China diverted an order placed by the British Royal Air Force for 100 Curtiss-Wright P-40B Tomahawks but buying airplanes was only a single essential step in producing a fighting air unit. Trained pilots were necessary, and rapidly, as tensions across the Pacific escalated. On April 15, 1941, President Franklin D. Roosevelt quietly signed an Executive Order permitting Chennault to recruit straight from the ranks of American military reserve pilots. Within a couple of months, 350 flyers joined from pursuit (fighter), bomber, and patrol squadrons. In all, about half the pilots in the Flying Tigers came from the U. S. Navy and Marine Corps although the Army Air Corps supplied 1-third. Factory test pilots at Bell, Consolidated, and other firms, and commercial airline pilots, filled the remaining slots.


The Flying Tigers flew their first mission on December 20. The unit’s name was derived from the ferocious fangs and teeth painted on the nose of AVG P-40s at either side of the distinctive, huge radiator air intake. The thought is stated to originate from photos in a magazine that showed Royal Air Force Tomahawks of No. 112 Squadron, operating in the western desert of North Africa, adorned with fangs and teeth painted around their air intakes. The Flying Tigers have been the initial genuine opposition the Japanese military encountered. In significantly less than 7 months of action, AVG pilots destroyed about 115 Japanese aircraft and lost only 11 planes in air-to-air combat. The AVG disbanded on July 4, 1942, and its assets, like a few pilots, became a element of the U. S. Army Air Forces (AAF) 23rd Fighter Group in the newly activated 14th Air Force. Chennault, now a Brigadier Common, assumed command of the 14th AF and by war’s finish, the 23rd was one particular of the highest-scoring Army fighter groups.


As wartime experience in the P-40 mounted, Curtiss produced numerous modifications. Engineers added armor plate, greater self-sealing fuel tanks, and more potent engines. They modified the cockpit to enhance visibility and changed the armament package to six, wing-mounted, .50 caliber machine guns. The P-40E Kittyhawk was the very first model with this gun package and it entered service in time to serve in the AVG. The final model created in quantity was the P-40N, the lightest P-40 constructed in quantity, and considerably faster than prior models. Curtiss built a single P-40Q. It was the quickest P-40 to fly (679 kph/422 mph) but it could not match the performance of the P-47 Thunderbolt and the P-51 Mustang so Curtiss ended development of the P-40 series with this model. In addition to the AAF, many Allied nations bought and flew P-40s which includes England, France, China, Russia, Australia, New Zealand, Canada, South Africa, and Turkey.


The Smithsonian P-40E did not serve in the U. S. military. Curtiss-Wright constructed it in Buffalo, New York, as Model 87-A3 and delivered it to Canada as a Kittyhawk IA on March 11, 1941. It served in No. 111 Squadron, Royal Canadian Air Force (RCAF). When the Japanese navy moved to attack Midway, they sent a diversionary battle group to menace the Aleutian Islands. Canada moved No. 111 Squadron to Alaska to assist defend the region. Soon after the Japanese threat diminished, the unit returned to Canada and ultimately transferred to England without its P-40s. The RCAF declared the NASM Kittyhawk IA surplus on July 27, 1946, and the aircraft ultimately returned to the United States. It had a number of owners before ending up with the Explorer Scouts youth group in Meridian, Mississippi. For the duration of the early 1960s, the Smithsonian began browsing for a P-40 with a documented history of service in the AVG but discovered none. In 1964, the Exchange Club in Meridian donated the Kittyhawk IA to the National Aeronautical Collection, in memory of Mr. Kellis Forbes, a regional man devoted to Boys Club activities. A U. S. Air Force Reserve crew airlifted the fighter to Andrews Air Force Base, Maryland, on March 13, 1964. Andrews personnel restored the airplane in 1975 and painted it to represent an aircraft of the 75th Fighter Squadron, 23rd Fighter Group, 14th Air Force.


• • •


Quoting from Wikipedia | Curtiss P-40 Warhawk:


The Curtiss P-40 Warhawk was an American single-engine, single-seat, all-metal fighter and ground attack aircraft that very first flew in 1938. It was utilized by the air forces of 28 nations, including those of most Allied powers throughout Planet War II, and remained in front line service until the end of the war. It was the third most-developed American fighter, right after the P-51 and P-47 by November 1944, when production of the P-40 ceased, 13,738 had been built, all at Curtiss-Wright Corporation‘s major production facility at Buffalo, New York.


The P-40 design and style was a modification of the preceding Curtiss P-36 this reduced development time and enabled a speedy entry into production and operational service.


Warhawk was the name the United States Army Air Corps adopted for all models, making it the official name in the United States for all P-40s. The British Commonwealth and Soviet air forces utilized the name Tomahawk for models equivalent to the P-40B and P-40C, and the name Kittyhawk for models equivalent to the P-40D and all later variants.


The P-40’s lack of a two-stage supercharger created it inferior to Luftwaffe fighters such as the Messerschmitt Bf 109 or the Focke-Wulf Fw 190 in higher-altitude combat and it was hardly ever used in operations in Northwest Europe. Amongst 1941 and 1944, however, the P-40 played a essential role with Allied air forces in 3 main theaters: North Africa, the Southwest Pacific and China. It also had a important part in the Middle East, Southeast Asia, Eastern Europe, Alaska and Italy. The P-40’s efficiency at high altitudes was not as critical in these theaters, exactly where it served as an air superiority fighter, bomber escort and fighter bomber.


P-40s 1st saw combat with the British Commonwealth squadrons of the Desert Air Force (DAF) in the Middle East and North African campaigns, in the course of June 1941. The Royal Air Force‘s No. 112 Squadron was among the first to operate Tomahawks, in North Africa, and the unit was the 1st to feature the &quotshark mouth&quot logo, copying comparable markings on some Luftwaffe Messerschmitt Bf 110 twin-engine fighters. [N 1]


Even though it gained a post-war reputation as a mediocre design and style, appropriate only for close air help, more recent analysis such as scrutiny of the records of person Allied squadrons indicates that the P-40 performed surprisingly properly as an air superiority fighter, at times suffering serious losses, but also taking a really heavy toll on enemy aircraft. The P-40 presented the added advantage of low expense, which kept it in production as a ground-attack fighter extended after it was obsolete in the air superiority part.


As of 2008, 19 P-40s were airworthy.


CN – Major Speedy Prototyping China Manufacturer Gives Higher Precision Metal

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Major Rapid Prototyping China Manufacturer Offers Higher Precision Metal

Guangzhou, China — (ReleaseWire) — 01/26/2015 — Guangzhou, China – As Western organizations demand for speedy prototyping increases, Klarm Prototyping has spent the last decade establishing itself as a leader among all Chinese fast prototyping firms.
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(Source from rapid prototyping from China blog)

Friday, November 28, 2014

Longgang Town - China Printing City - Sheet Metal Fabrication Manufacturer - China Sheet Metal

The traditional sources of stream length printing industry


In the very first “country” Font Size “Gold Card” started, Longgang town to show the world they had just won a “country” Font Size “gold card “—- China Printing City. Longgang town committee secretary Liang Shisheng stated: “The city from farmers to print the city, marking the Longgang’s improvement has entered a new phase, to find a commence point of new improvement.”


Wenzhou Printing has gone through centuries of ups and downs. According to the neighborhood men and women told reporters that: “As early as 1895, Ryan, who Han Lee West, Lee Messina brothers to lithography planes into the hands of Wenzhou, in the Ryan set up outdoors the neighborhood Temple, printing, right after which letterpress printing tactics and casting methods have pass the word into the Wenzhou. “to early 1949, a total of Wenzhou printer (shops) and far more than 40, all kinds of printing equipment, about 110 units, employing about 190 people formed a specific scale and influence. Right after the reform and opening up, Wenzhou, non-public financial structure of the printing enterprise mushroomed initial emerged. At present, the printing sector in Wenzhou City, the country’s total output worth of 4.5%.


Multi-brand to attract investment in


At present, Longgang town of “China Printing City” this gold card for the new development starting points in the printing market to attain more quickly development and higher expansion, another advantage of the improvement of new Longgang. Longgang town mayor, said Tang Baolin, use the “construction zone, adjusting the structure, playing brand, innovation, grasping the environment” such as the five “tricks” to speed up the printing qualities of industrial improvement. At present, an area of five square kilometers in the printing market base is arranging to construct them.


It is understood that Maotai, Pierre Cardin, clean, L’Oreal, Aokang, BAOXINIAO branded merchandise such as packaging and printing are all derived from Longgang, which makes the “China Printing City” brand has already begun to play. “Not only the concentration of Longgang into printing businesses print Town, and is the industry’s very best investment environment in print the city.” Longgang town proposed a new slogan.




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Sunday, October 5, 2014

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Saturday, October 4, 2014

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Saturday, September 27, 2014

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Sunday, September 21, 2014

Newest Machining Elements Manufacturer News

Southeastern Technology finds future of manufacturing

When it opened in 1982, Southeastern Technologies workers produced by hand components with tool and die machines and industrial grinders. &quotThirty years ago this is what manufacturing was,&quot SET Business Development Chief Michael Spencer stated pointing to a an&nbsp…
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Johnson hits Gov. Dayton on overall health care

He appeared at Mack Engineering — a modest Minneapolis manufacturing company of machined components for businesses such as John Deere and Honeywell – where co-owner Jennifer Salisbury stated her organization was experiencing skyrocketing overall health&nbsp…
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Waterjet Manufacturer Jet Edge Launches New Web site



St. Michael, Minnesota (PRWEB) September 19, 2014


Jet Edge, Inc., a world-leading manufacturer of ultra-higher stress water jet technology, not too long ago launched a new website at http://www.jetedge.com.


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Featuring multilingual content and a contemporary design that functions across devices, the new jetedge.com offers rapidly and intuitive access to Jet Edge’s diverse item line as well as in depth details about waterjet’s numerous applications. The content-rich site also attributes a resource center for waterjet operators, enhanced search capabilities, consumer achievement stories and testimonials, and easy access to Jet Edge’s on the web waterjet components store and upkeep training registration.


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“Our new web site was made with our consumers foremost in mind,” stated Nancy Lauseng, Jet Edge marketing manager. “We are a worldwide organization with growing international sales. One particular of our largest priorities was producing the web site obtainable in many languages. We also wanted the internet site to function effectively on any device, be it a Pc or smartphone. To enhance our visitors’ general encounter, we’ve tremendously enhanced our product presentations, incorporating more pictures, videos and application examples, and we’ve produced the site less difficult to navigate and search. By consumer demand, we have added extra resources and tech ideas for Jet Edge waterjet operators.”


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The foreign language platform of Jet Edge’s new internet site initially will feature foreign language translations utilizing Google Translate. Jet Edge is developing professionally translated sites for its key international markets.


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About Jet Edge&#13

Established in 1984, Jet Edge is celebrating its 30th anniversary in 2014. Jet Edge is a worldwide designer and manufacturer of waterjet systems for precision cutting, surface preparation and coating removal. Jet Edge systems are utilised about the planet in a broad range of industries, from the world’s leading airlines to automotive, aerospace, industrial producers, machine and job shops.


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Monday, September 8, 2014

Gortite, Gortrac Join Six Firms to Type U.S. Biggest Manufacturer of Dynamic Gear Protection



New Berlin, WI (PRWEB) September 08, 2014


NEW BERLIN, Wis., Sep 8, 2014 – Industrial protection producer A&ampA Manufacturing nowadays announced that it has chosen a new trade name and brand mark, as Gortite and Gortrac combine with the organization’s other six firms to produce the new enterprise entity Dynatect Manufacturing, Inc. With seven manufacturing plants and two distribution locations worldwide, Dynatect is the biggest manufacturer of dynamic industrial gear protection in the U.S. and solves applications worldwide through their extensive item supplying.



The move comes as Dynatect reveals a approach to focus on seven crucial markets: Machine Tool Healthcare Automation Oil and Gas Building and Agriculture Transportation and MRO.



Mentioned Dynatect Chief Executive Officer Brian McSharry, “Today’s launch reflects how we’ve actually been working for years. While we utilised to front the market with a number of various organizations, we’ve really constantly been a single 1-stop shop for the whole gamut of industrial equipment protection. Engineers and technical field advisors across all firms have liaised closely to provide the optimal solution for every distinctive application. Nonetheless, the a lot of businesses involved admittedly created for some confusion among our customers. Dynatect resolves that issue.”



The collaboration of the former group of firms has resulted in a portfolio of a lot more than 500,000 customized designs, which Dynatect will provide in four distinct solution categories: protective coverings, cable and hose carriers, mechanical motion manage, and elastomer components.



“It’s all about achieving a clearer enterprise supplying,” said Senior Vice President Tony Cavalco. “We have observed significant growth by means of new product development and acquisitions over the last four years. We had been clearly doing one thing proper. Now, we’ve taken the time necessary to identify what underpins this accomplishment. We are confident we can preserve good quality and innovation as we combine our capabilities into a single, unified organization which will concentrate on enhanced sales into targeted industries.”



Industry-recognized brands Gortite, Gortrac and Polyclutch, will stay as item variety labels of Dynatect. Explains McSharry, “These brands have been around for so extended, they’re component of U.S. industrial history, and we want folks to know that Dynatect will honor their legacy. We will continue the tradition of vertical integration and commitment to high quality that our founder Gerald O’Rourke began back in the 1940s. These values have led to Gortite right now obtaining a 60% share in the extremely competitive domestic U.S. marketplace, and they are bound to lead to even higher successes as we move forward as Dynatect on the international market.”



Businesses acquired by A&ampA since 2012 will continue to carry their brand names due to the name recognition in the marketplace: U.S acquisitions Ro-Lab, Lead Screws International, and German acquisitions MFB, and Halltech.



About Dynatect Manufacturing, Inc.


Established as A&ampA Manufacturing in 1945, Dynatect manufactures dynamic industrial protection for gear and individuals. The firm is headquartered in New Berlin, Wis., and operates eight manufacturing facilities across North America, Europe and Asia. Serving the key markets of Health-related Automation Oil and Gas Construction and Agriculture Machine Tool Transportation and Maintenance, Repair and Operations (MRO). Dynatect offers four item groups: protective coverings cable and hose carriers mechanical motion control and elastomer components. Its portfolio at present includes a total of over 500,000 customized designs, such as the Gortite, Gortrac and Polyclutch solution ranges.



http://www.dynatect.com



Dynatect Manufacturing, Inc.


2300 South Calhoun Road


New Berlin, WI 53151


telephone: +1 262 786-1500


fax: +1 262 786-3280





















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Sunday, September 7, 2014

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Friday, September 5, 2014

Latest Manufacturer Of Precision Machined Components News

Weimer Bearing &amp Transmission plans new HQ in Germantown

The firm has numerous sister firms below the Weimer Industries umbrella of organizations: Wisconsin Stamping and Manufacturing – a manufacturer of precision tubular stampings, raschig rings and machined components DexM Corp. – a manufacturer&nbsp…
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Precision Engineered Items LLC acquires brands Holmed, HowesTemco

Precision Engineered Merchandise LLC (PEP), a global manufacturer of precision plastic and metal elements and devices, has completed acquisition of Advanced Precision Items (APP) organization divisions Holmed, HowesTemco, Premco and Profiles. The 4 …
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Most current Cnc Turned Components Manufacturer News

Supplier to talk about space exploration projects at IMTS 2014

Moorpark, California – Gibbs and Associates, developer of GibbsCAM computer software for programming CNC machine tools and a Cimatron company, will host Rodney Babcock, president and owner of Subsequent Intent, who will deliver a presentation in the Gibbs and&nbsp…
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Monday, September 1, 2014

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Friday, August 29, 2014

Smoke Bomb - China Turned Components - Hydraulic Couplings Manufacturer


Please aid improve this write-up by adding trustworthy references. Unsourced material may be challenged and removed. (June 2009)

Home made smoke powder burning.

A smoke bomb is a firework created to create smoke upon ignition. Smoke bombs are valuable to military units, airsoft games, paintball games,self defense and pranks. Even though there are smoke-generating devices that are dropped from airplanes, the term “smoke bomb” is utilised to describe the three sorts of devices:

A smoke ball is a hollow, cherry-sized sphere of brightly colored clay or cardboard filled with a smoke-generating composition that produces a forceful jet of colored smoke for ten to 15 seconds.

The usual chemical equation is 9.6KNO3 + C12H22O11 4.8K2CO3 + 7.2CO2 + 11H2O + 4.8N2.

A smoke candle (also known as a smoke generator or smoke canister) is a cylindrical cardboard tube with a fuse, typically 1 inches (37 mm) in diameter and several inches lengthy and resembling a giant firecracker. Such a device creates a thick cloud of smoke for up to several minutes. Utilizes consist of providing smoke for smoke testing and producing a smoke-screen for paintball and airsoft games.

A smoke canister (or smoke grenade) is a metal can that releases smoke when a pin is pulled. Utilized by military personnel for signalling or as a screening device for troop movements.

Colored smoke devices use a formula that consists of an oxidizer (typically potassium chlorate, KClO3), a fuel (normally sugar), a moderant (such as sodium bicarbonate) to keep the reaction from getting also hot, and a powdered organic dye. The burning of this mixture evaporates the dye and forces it out of the device, where it condenses in the atmosphere to form a “smoke” of finely dispersed particles.

Other signifies of smoke bombs are generally generated in two broadly identified ways: cutting up tiny size pieces of a ping pong, ball placing inside of a closed container, and igniting it or mixing the chemicals kno3(potassium nitrate) and sugar although lightly heated in a pan until the mixture begins to type a peanut butter like substance and letting cool.

Devices or cartridges containing only the dye are employed with an external heat supply in a smoke machine.

In the military, smoke bombs are a signifies for creating smoke-screens.

Smoke bombs are frequently sold as consumer fireworks, but smoke grenades (with pins rather than external fuses) are not deemed fireworks and are typically not sold at fireworks shops. The military-style smoke grenades also expense much far more than smoke bomb fireworks. Military-style smoke grenades typically expense about $ five-$ 40 USD, while smoke bombs typically price around two to three dollars each and every.

External hyperlinks

Smoke bomb details &amp Guides.

A pyroguide on pyrotechics has much more data on smoke bombs.

Birthplace of the “Legendary Smokebomb” complete guide on its manufacture. (Although it has the exact same ingredients as another well identified mixture, the ratio of ingredients and approach to make it are what make it diverse.)

Categories: Fireworks | Pyrotechnics | SmokeHidden categories: Articles needing extra references from June 2009 | All articles needing further references




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Wednesday, August 20, 2014

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Friday, August 15, 2014

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Ethane - Turned Parts - Cnc China Machining Parts Manufacturer


History

Ethane was first synthetically created in 1834 by Michael Faraday, applying electrolysis of a potassium acetate solution. He mistook the hydrocarbon product of this reaction for methane, and did not investigate it further. During the period 18471849, in an effort to vindicate the radical theory of organic chemistry, Hermann Kolbe and Edward Frankland produced ethane by the reductions of propionitrile (ethyl cyanide) and ethyl iodide with potassium metal, and, as did Faraday, by the electrolysis of aqueous acetates. They, however, mistook the product of these reactions for methyl radical, rather than the dimer of methyl, ethane. This error was corrected in 1864 by Carl Schorlemmer, who showed that the product of all these reactions was in fact ethane.

Its name was made from the name of ether, which at first meant diethyl ether.

Chemistry

In the laboratory, ethane may be conveniently prepared by Kolbe electrolysis. In this technique, an aqueous solution of an acetate salt is electrolysed. At the anode, acetate is oxidized to produce carbon dioxide and methyl radicals, and the highly reactive methyl radicals combine to produce ethane:

CH3COO CH3 + CO2 + e

CH3 + CH3 C2H6

Another method, the oxidation of acetic anhydride by peroxides, is conceptually similar.

The chemistry of ethane also involves chiefly free radical reactions. Ethane can react with the halogens, especially chlorine and bromine, by free radical halogenation. This reaction proceeds through the propagation of the ethyl radical:

C2H5 + Cl2 C2H5Cl + Cl

Cl + C2H6 C2H5 + HCl

Because halogenated ethanes can undergo further free radical halogenation, this process results in a mixture of several halogenated products. In the chemical industry, more selective chemical reactions are used for the production of any particular two-carbon halocarbon.

Combustion

The complete combustion of ethane releases 1561 kJ/mol, or 51.9 kJ/g, of heat, and produces carbon dioxide and water according to the chemical equation

2 C2H6 + 7 O2 4 CO2 + 6 H2O + 3170 kJ/mol

Combustion occurs by a complex series of free-radical reactions. Computer simulations of the chemical kinetics of ethane combustion have included hundreds of reactions. An important series of reaction in ethane combustion is the combination of an ethyl radical with oxygen, and the subsequent breakup of the resulting peroxide into ethoxy and hydroxyl radicals.

C2H5 + O2 C2H5OO

C2H5OO + HR C2H5OOH + R

C2H5OOH C2H5O + OH

The principal carbon-containing products of incomplete ethane combustion are single-carbon compounds such as carbon monoxide and formaldehyde. One important route by which the carbon-carbon bond in ethane is broken to yield these single-carbon products is the decomposition of the ethoxy radical into a methyl radical and formaldehyde, which can in turn undergo further oxidation.

C2H5O CH3 + CH2O

Some minor products in the incomplete combustion of ethane include acetaldehyde, methane, methanol, and ethanol. At higher temperatures, especially in the range 600900 C, ethylene is a significant product. It arises via reactions like

C2H5 + O2 C2H4 + OOH

Similar reactions (although with species other than oxygen as the hydrogen abstractor) are involved in the production of ethylene from ethane in steam cracking.

Production

After methane, ethane is the second-largest component of natural gas. Natural gas from different gas fields varies in ethane content from less than 1% to over 6% by volume. Prior to the 1960s, ethane and larger molecules were typically not separated from the methane component of natural gas, but simply burnt along with the methane as a fuel. Today, however, ethane is an important petrochemical feedstock, and it is separated from the other components of natural gas in most well-developed gas fields. Ethane can also be separated from petroleum gas, a mixture of gaseous hydrocarbons that arises as a byproduct of petroleum refining. Economics of building and running processing plants can change, however. If the relative value of sending the unprocessed natural gas to a consumer exceeds the value of extracting ethane, then the plant may not be run. This can cause operational issues managing the changing quality of the gas in downstream systems.

Ethane is most efficiently separated from methane by liquefying it at cryogenic temperatures. Various refrigeration strategies exist: the most economical process presently in wide use employs turboexpansion, and can recover over 90% of the ethane in natural gas. In this process, chilled gas expands through a turbine; as it expands, its temperature drops to about -100 C. At this low temperature, gaseous methane can be separated from the liquefied ethane and heavier hydrocarbons by distillation. Further distillation then separates ethane from the propane and heavier hydrocarbons

Uses

The chief use of ethane is in the chemical industry in the production of ethylene by steam cracking. When diluted with steam and briefly heated to very high temperatures (900 C or more), heavy hydrocarbons break down into lighter hydrocarbons, and saturated hydrocarbons become unsaturated. Ethane is favored for ethylene production because the steam cracking of ethane is fairly selective for ethylene, while the steam cracking of heavier hydrocarbons yields a product mixture poorer in ethylene, and richer in heavier olefins such as propylene and butadiene, and in aromatic hydrocarbons.

Experimentally, ethane is under investigation as a feedstock for other commodity chemicals. Oxidative chlorination of ethane has long appeared to be a potentially more economical route to vinyl chloride than ethylene chlorination. Many processes for carrying out this reaction have been patented, but poor selectivity for vinyl chloride and corrosive reaction conditions (specifically, a hydrochloric acid-containing reaction mixture at temperatures greater than 500 C) have discouraged the commercialization of most of them. Presently, INEOS operates a 1000 t/a ethane-to-vinyl chloride pilot plant at Wilhelmshaven in Germany.

Similarly, the Saudi Arabian firm SABIC has announced construction of a 30,000 t/a plant to produce acetic acid by ethane oxidation at Yanbu. This economic viability of this process may rely on the low cost of ethane near Saudi oil fields, and it may not be competitive with methanol carbonylation elsewhere in the world.

Ethane can be used as a refrigerant in cryogenic refrigeration systems. On a much smaller scale, in scientific research, liquid ethane is used to vitrify water-rich samples for electron microscopy. A thin film of water, quickly immersed in liquid ethane at -150 C or colder, freezes too quickly for water to crystallize. This rapid freezing does not disrupt the structure of soft objects present in the liquid state, as the formation of ice crystals can do.

Health and safety

At room temperature, ethane is a flammable gas. When mixed with air at 3.0% 12.5% by volume, it forms an explosive mixture.

Some additional precautions are necessary where ethane is stored as a cryogenic liquid. Direct contact with liquid ethane can result in severe frostbite. In addition, the vapors evaporating from liquid ethane are, until they warm to room temperature, heavier than air and can creep along the ground or gather in low places, and if they encounter an ignition source, can flash back to the body of ethane from which they evaporated.

Containers recently emptied of ethane may contain insufficient oxygen to support life. Beyond this asphyxiation hazard, ethane poses no known acute or chronic toxicological risk. It is not known or suspected to be a carcinogen.

Atmospheric and extraterrestrial ethane

A photograph of Titan’s northern latitudes. The dark features appear to be hydrocarbon lakes, but further images will be needed to see if the dark spots remain the same (as they would if they were lakes)

Ethane occurs as a trace gas in the Earth’s atmosphere, currently having a concentration at sea level of 0.5 ppbv, though its pre-Industrial concentration is likely to have been lower since a significant proportion of the ethane in today’s atmosphere may have originated as fossil fuels. Although ethane is a greenhouse gas, it is much less abundant than methane and also less efficient relative to mass. It has also been detected as a trace component in the atmospheres of all four giant planets, and in the atmosphere of Saturn’s moon Titan.

Atmospheric ethane results from the Sun’s photochemical action on methane gas, also present in these atmospheres: ultraviolet photons of shorter wavelengths than 160 nm can photo-dissociate the methane molecule into a methyl radical and a hydrogen atom. When two methyl radicals recombine, the result is ethane:

CH4 CH3 + H

CH3 + CH3 C2H6

In the case of Titan, it was once widely hypothesized that ethane produced in this fashion rained back onto the moon’s surface, and over time had accumulated into hydrocarbon seas or oceans covering much of the moon’s surface. Infrared telescopic observations cast significant doubt on this hypothesis, and the Huygens probe, which landed on Titan in 2005, failed to observe any surface liquids, although it did photograph features that could be presently dry drainage channels. In December 2007 the Cassini probe found at least one lake at Titan’s south pole, now called Ontario Lacus because of the lake’s similar area to Lake Ontario on Earth (approximately 20,000 km). Further analysis of infrared spectroscopic data presented in July 2008 provided stronger evidence for the presence of liquid ethane in Ontario Lacus.

In 1996, ethane was detected in Comet Hyakutake, and it has since been detected in some other comets. The existence of ethane in these distant solar systembodies may implicate ethane as a primordial component of the solar nebula from which the sun and planets are believed to have formed.

In 2006, Dale Cruikshank of NASA/Ames Research Center (a New Horizons co-investigator) and his colleagues announced the spectroscopic discovery of ethane on Pluto’s surface.

References

^ Trace gases

^ http://www.nature.com/nature/journal/v454/n7204/abs/nature07100.html

^ A. Stern (November 1, 2006). “Making Old Horizons New”. The PI’s Perspective. Johns Hopkins University Applied Physics Laboratory. http://pluto.jhuapl.edu/overview/piPerspectives/piPerspective_11_1_2006.php. Retrieved 2007-02-12. 

Michael Faraday (1834). Experimental researches in electricity: Seventh series. Philosophical Transactions, 124:77122.

Hermann Kolbe, Edward Frankland (1849). On the products of the action of potassium on cyanide of ethyl. Journal of the Chemical Society, 1:6074.

Edward Frankland (1850). On the isolation of the organic radicals. Journal of the Chemical Society, 2:263296.

Hermann Kolbe (1850). Researches on the electrolysis of organic compounds. Journal of the Chemical Society, 2:157184.

Carl Schorlemmer (1864). Annalen der Chimie, 132:234.

Michael J. Mumma et al. (1996). Detection of Abundant Ethane and Methane, Along with Carbon Monoxide and Water, in Comet C/1996 B2 Hyakutake: Evidence for Interstellar Origin. Science, 272:13101314.

Bob Brown et al. (2008). NASA Confirms Liquid Lake on Saturn Moon.

External links

Wikimedia Commons has media related to: Ethane

International Chemical Safety Card 0266

Computational Chemistry Wiki

Market-Driven Evolution of Gas Processing Technologies for NGLs

Staggered and eclipsed ethane

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Alkanes

Methane (CH4)  Ethane (C2H6)  Propane (C3H8)  Butane (C4H10)  Pentane (C5H12)  Hexane (C6H14)  Heptane (C7H16)  Octane (C8H18)  Nonane (C9H20)  Decane (C10H22)  Undecane (C11H24)  Dodecane (C12H26)

Higher alkanes  List of alkanes

Categories: AlkanesHidden categories: Chemboxes which contain changes to watched fields




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